專家信息：
曹勇，1973年出生，江蘇泗陽人，畢業于復旦大學化學系。現任復旦大學化學系教授，博士生導師。主要從事表面化學和多相催化研究，涉及納米金屬催化、固體酸堿催化、低碳烷烴的定向活化及選擇氧化、生物質催化轉化及其高附加值利用等領域。2014年獲得第五屆“中國催化青年獎”。
教育及工作經歷：
1990年9月至1995年7月 復旦大學化學系，獲理學學士學位。
1998年3月至2000年1月 新加坡國立大學理學院化學系，研究生聯合培養。
1994年9月至2000年7月 復旦大學化學系，獲理學博士學位。
2000年8月至2001年11月 復旦大學化學系工作，講師。
2001年12月至2005年5月 復旦大學化學系工作，副教授/碩士生導師。
2005年6月至今 復旦大學化學系工作，教授/博士生導師。
學術兼職及社會任職：
1、2009年5月 至今 被聘為 Applied Catalysis A: General 編委。
2、2014年9月 至今 被聘為 《催化學報》編委。
3、參與J. Am. Chem. Soc.、J. Catal.和《高等學校化學學報》、《化學學報》、《物理化學學報》、《石油化工》等刊物的審稿。
主講課程：
1、《現代化學專題-表面化學》
2、《物理化學（II）》
3、《催化反應機理》（研）
4、《高等結構分析》（工程碩士）
培養研究生情況：
指導研究生多名，其中3名已獲碩士學位。
研究方向：
主要從事表面化學和多相催化研究，涉及高性能新結構納米介孔催化材料的創制與綠色催化應用、低碳烷烴選擇氧化制烯烴、1,3-丙二醇等聚酯原料關鍵單體的催化加氫合成、金屬/半導體光催化、催化過程的原位動態譜學表征及C1資源的綜合利用等。
承擔科研項目情況：
主持在研或完成國家科技部863項目、國家自然科學基金重點項目、國家自然科學基金創新群體資助項目、上海市"青年科技啟明星計劃跟蹤"等十余項科研項目。
1.核-殼式納米復合催化劑的設計合成及其分子識別催化性。
2.新型金屬/有機雜化催化劑的設計及直接法制H2O2研究。
3.甲醇氧化羰化制碳酸二甲酯新型納米復合催化劑研究。
科研成果：
1 在新型納米催化材料的研制及應用、催化原位譜學表征和催化理論的研究方面取得了一定的成果在Acc. Chem. Res.,Angew. Chem. Int. Ed., J. Am. Chem. Soc., Chem. Europ. J.,ChemSusChem,Chem. Commun., Green Chem., J. Catal., Adv. Synth. Catal., Langmuir等學術期刊發表SCI論文180余篇，他引3000余次。
2.申請中國發明專利32件(授權專利18件)。
2001年至今發表在Acc. Chem. Res.,Angew. Chem. Int. Ed., J. Am. Chem. Soc., Chem. Europ. J.,ChemSusChem,Chem. Commun., Green Chem., J. Catal., Adv. Synth. Catal., Langmuir等學術期刊發表SCI論文180余篇，其中影響因子大于 3.0 論文 50 余篇，SCI他引3000 余次，10篇論文被他引40次以上，其中單篇最高他引過百次。
近5年發表論文：
2015
1. Gold-Catalyzed Reductive Transformation of Nitro Compounds Using Formic Acid: Mild, Efficient, and Versatile, L. Yu, Q. Zhang, S. S. Li, J. Huang, Y. M. Liu, H. Y. He, Y. Cao*,ChemSusChem 2015, 8, 3029-3035. [PDF] [SI]
2. Formic Acid: A Versatile Renewable Reagent for Green ans Sustainable Chemical Syhthesis, X. Liu, S. S. Li, Y. M. Liu, Y. Cao*, Chin. J. Catal. 2015, 36, 1461-1475. [PDF]
3. Deoxygenative Coupling of Nitroarenes to Synthesize Aromatic Azo Compounds with CO Using Supported Gold Catalysts, H. Q. Li, X. Liu, Q. Zhang, S. S. Li, Y. M. Liu, Y. Cao*,Chem. Commun. 2015, 51, 11217-11220. [PDF] [SI]
4. Heterogeneous Gold-Catalyzed Selective Reductive Transformation of Quinolines with Formic Acid, L. Tao, Q. Zhang, S. S. Li, X. Liu, Y. M. Liu, Y. Cao*, Adv. Synth. Catal.2015, 357, 753-760. [PDF] [SI]
2014
1. An Aqueous Rechargeable Formate-based Hydrogen Battery Driven by Heterogeneous Pd Catalysis, Q. Y. Bi, J. D. Lin, Y. M. Liu, X. L. Du, H. Y. He, Y. Cao*, Angew. Chem. Int. Ed. 2014, 53, 13583-13587. [PDF] [SI]
2. Gold-catalyzed Direct Hydrogenative Coupling of Nitroarenes to Synthesize Aromatic Azo Compounds, X. Liu, H. Q. Li, S. Ye, Y. M. Liu, H. Y. He, Y. Cao*, Angew. Chem. Int. Ed.2014, 53,7624-7628. [PDF] [SI]
3. Gold Supported on Titania for Specific Monohydrogenation of Dinitroaromatics in the Liquid Phase, S. S. Liu, X. Liu, L.Yu, Y. M. Liu*, H. Y. He, Y. Cao*, Green Chem. 2014,16, 4162-4169. [PDF] [SI]
4. Partially Reduced Iridium Oxide Clusters Dispersed on Titania as Efficient Catalyst for Facile Synthesis of Dimethylformamide from CO2, H2 and Dimethylamine, Q. Y. Bi, J. D. Lin, Y. M. Liu, S. H. Xie, H. Y. He, Y. Cao*, Chem. Commun. 2014, 50, 9138-9140. [PDF] [SI]
5. Efficient and Exceptionally Selective Semireduction of Alkynes using a Supported Gold Catalyst under a CO Atmosphere, S. S. Li, X. Liu, Y. M. Liu*, H. Y. He, K. N. Fan, Y. Cao*,Chem. Commun. 2014, 50, 5626-5628. [PDF] [SI]
6. Propylene from Renewable Resources: Catalytic Conversion of Glycerol into Propylene, L. Yu, J. Yuan, Q. Zhang, Y. M. Liu, H. Y. He, K. N. Fan, Y. Cao*, ChemSusChem 2014, 7, 743-747. [PDF] [SI]
7. Supported Gold Catalysis: From Small Molecule Activation to Green Chemical Synthesis, X. Liu, L. He, Y. M. Liu, Y. Cao*, Acc. Chem. Res. 2014, 47, 793-804. [PDF]
2013
1. Efficient Catalytic Hydrogenolysis of Glycerol using Formic Acid as Hydrogen Source, J. Yuan, S. S. Li, L. Yu, Y. M. Liu, Y. Cao*, Chinese J. Catal. 2013, 34, 2066–2074. [PDF]
2. Catalytic Conversion of Biomass-derived Levulinic Acid into γ-valerolactone using Iridium Nanoparticles Supported on Carbon Nanotubes, X. L. Du, Y. M. Liu, J. Q. Wang, Y. Cao*, K. N. Fan, Chinese J. Catal. 2013, 34, 993–1001. [PDF]
3. Mild, Selective and Switchable Transfer Reduction of Nitroarenes Catalyzed by Supported Gold Nanoparticles, X. Liu, S. Ye, H. Q. Li, Y. M. Liu, Y. Cao*, K. N. Fan, Catal. Sci. Technol. 2013, 3, 3200-3206. [PDF] [SI]
4. C-C Cross-Coupling of Primary and Secondary Benzylic Alcohols using Supported Gold-Based Bimetallic Catalysts, X. Liu, R. S. Ding, L. He, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, ChemSusChem 2013, 6, 604-608. [PDF] [SI]
5. Sucrose-templated Mesoporous β-Ga2O3 as a Novel Efficient Catalyst for Dehydrogenation of Propane in the Presence of CO2, J. L. Wu, M. Chen, Y. M. Liu*, Y. Cao*, H. Y. He, K. N. Fan, Catal. Commun. 2013, 30, 61-65. [PDF]
6. A Versatile Aqueous Reduction of Bio-based Carboxylic Acids using Syngas as a Hydrogen Source, L. Yu, X. L. Du, J. Yuan, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan,ChemSusChem 2013, 6, 42-46. [PDF] [SI]
7. Copper-based Catalysts for the Efficient Conversion of Carbohydrate Biomass into γ-valerolactone in the Absence of Externally Added Hydrogen, J. Yuan, S. S. Li, L. Yu, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Energy Environ. Sci. 2013, 6, 3308-3313. [PDF] [SI]
2012
1. Tunable Copper-catalyzed Chemoselective Hydrogenolysis of Biomass-derived γ-valerolactone into 1,4-pentanediol or 2-methyltetrahydrofuran, X. L. Du, Q. Y. Bi, Y. M. Liu, Y. Cao* H. Y. He, K. N. Fan, Green Chem. 2012, 14, 935-939. [PDF] [SI]
2. Graphite Oxide as an Efficient and Durable Metal-free Catalyst for Aerobic Oxidative Coupling of Amines to Imines, H. Huang, J. Huang, Y. M. Liu*, H. Y. He, Y. Cao*, K. N. Fan, Green Chem. 2012, 14, 930-934. [PDF] [SI]
3. Highly Efficient Heterogeneous Gold-catalyzed Direct Synthesis of Tertiary and Secondary Amines from Alcohols and Urea, L. He, Y. Qian, R. S. Ding, Y. M. Liu, H. Y. He, K. N. Fan, Y. Cao*, ChemSusChem 2012, 5, 621-624. [PDF]
4. A General and Efficient Heterogeneous Gold-Catalyzed Hydration of Nitriles in Neat Water under Mild Atmospheric Conditions, Y. M. Liu, L. He, M. M. Wang, Y. Cao*, H. Y. He, K. N. Fan, ChemSusChem 2012, 5, 1392-1396. [PDF] [SI]
5. Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions, Q. Y. Bi, X. L. Du, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, J. Am. Chem. Soc. 2012, 134, 8926-8933. [PDF] [SI]
6. An Unusual Chemoselective Hydrogenation of Quinoline Compounds using Supported Gold Catalysts, D. Ren, L. He, L. Yu, R. S. Ding, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan,J. Am. Chem. Soc. 2012, 134, 17592-17598. [PDF] [SI]
2011
1. The Catalytic Use of Supported Gold Nanoparticles for Styrene Synthesis via Oxidative Dehydrogenation of Ethylbenzene, J. Xu, J. Huang, Y. M. Liu, Y. Cao*, Y. X. Li, K. N. Fan,Catal. Lett. 2011, 141, 198-206. [PDF]
2. Single-crystal-like Titania Mesocages, Z. F. Bian, J. Zhu, J. Wen, F. L. Cao, Y. N. Huo, X. F. Qian, Y. Cao, M. Q. Shen, H. X. Li, Y. F. Lu, Angew. Chem. Int. Ed. 2011, 50, 1105-1108. [PDF] [SI]
3. Dehydrogenation of Propane in the Presence of N2O over In2O3-Al2O3 Mixed Oxide Catalysts, M. Chen, J. L. Wu, Y. M. Liu, Y. Cao*, K. N. Fan, Catal. Commun. 2011, 12, 1063-1066. [PDF]
4. Mild and Efficient CO-mediated Eliminative Deoxygenation of Epoxides Catalyzed by Supported Gold Nanoparticles, J. Ni, L. He, Y. Cao*, H. Y. He, K. N. Fan, Chem. Commun. 2011, 47, 812-814. [PDF] [SI]
5. Gold Nanoparticles Supported on Hydroxylapatite as High Performance Catalysts for Low Temperature CO Oxidation, J. Huang, L. C. Wang, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Appl. Catal. B: Environ. 2011, 101, 560-569. [PDF]
6. Highly Chemo- and Regioselective Transfer Reduction of Aromatic Nitro Compounds using Ammonium Formate Catalyzed by Supported Gold Nanoparticles, X. B. Lou, L. He, Y. Qian, Y. M. Liu, Y. Cao*, K. N. Fan, Adv. Synth. Catal. 2011, 353, 281-286.[PDF] [SI]
7. Direct One-pot Reductive N-alkylation of Nitroarenes using Alcohols with Supported Gold Catalysts, C. H. Tang, L. He, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Chem. Eur. J. 2011,17, 7172-7177. [PDF] [SI]
8. Hydrogen-independent Reductive Transformation of Carbohydrate Biomass into γ-Valerolactone and Pyrrolidone Derivatives using Supported Gold Catalysts, X. L. Du, L. He, S. Zhao, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Angew. Chem. Int. Ed. 2011, 50, 7815-7819. [PDF] [SI]
9. Direct One-pot Reductive Imination of Nitroarenes using Aldehydes and Carbon Monoxide by Titania Supported Gold Nanoparticles at Room Temperature, J. Huang, Lei Yu, L. He, Y. M. Liu, Y. Cao*, K. N. Fan, Green Chem. 2011, 13, 2672-2677. [PDF] [SI]
10. Titania Supported Iridium Subnanoclusters as an Efficient Heterogeneous Catalyst for Direct Synthesis of Quinolines from Nitroarenes and Aliphatic Alcohols, L. He, J. Q. Wang, Y. Gong, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Angew. Chem. Int. Ed. 2011, 50, 10216-10220. [PDF] [SI]
11. Conversion of Biomass-derived Levulinate and Formate Esters into γ-valerolactone over Supported Gold Catalysts, X. L. Du, Q. Y. Bi, Y. M. Liu, Y. Cao*, K. N. Fan,ChemSusChem 2011, 4, 1838-1843. [PDF] [SI]
12. Gold Supported on Mesostructured Ceria as an Efficient Catalyst for the Chemoselective Hydrogenation of Carbonyl Compounds in Neat Water, M. M. Wang, L. He, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Green Chem. 2011, 13, 602-607. [PDF]
2011年以后發表論文：
2010
1. Supported Indium Oxide as Novel Efficient Catalysts for Dehydrogenation of Propane with Carbon Dioxide, M. Chen, J. Xu, Y. M. Liu, Y. Cao*, H. Y. He, J. H. Zhuang*, Appl. Catal. A: Gen. 2010, 377, 35-41. [PDF]
2. A Novel Gold-catalyzed Chemoselective Reduction of α,β-unsaturated Aldehydes using CO and H2O as the Hydrogen Source, L. He, F. J. Yu, X. B. Lou, Y. Cao*, H. Y. He, K. N. Fan, Chem. Commun. 2010, 46, 1553-1555. [PDF] [SI]
3. Dehydrogenation of Propane over In2O3–Al2O3 Mixed Oxide in the Presence of Carbon Dioxide, M. Chen, J. Xu, Y. M. Liu, Y. Cao*, H. Y. He, J. H. Zhuang*, J. Catal. 2010, 272, 101-108. [PDF]
4. Synthesis of Novel Cage-like Mesoporous Vanadosilicate and Its Efficient Performance for Oxidation Dehydrogenation of Propane, Y. M. Liu*, S. H. Xie, Y. Cao*, H. Y. He, K. N. Fan, J. Phys. Chem. C 2010, 114, 5941-5946. [PDF]
5. Efficient and Clean Gold-catalyzed One-pot Selective N-Alkylation of Amines with Alcohols, L. He, X. B. Lou, J. Ni, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Chem. Eur. J.2010, 16, 13965-13969. [PDF] [SI]
6. Facile Synthesis of Highly Stable and Well-dispersed Mesoporous ZrO2 Carbon Composites with High Performance in Oxidative Dehydrogenation of Ethylbenzene, Q. Li, J. Xu, Z. X. Wu, Dan Feng, J. P. Yang, J. Wei, Q. L. Wu, B. Tu, Y. Cao, D. Y. Zhao, Phys. Chem. Chem. Phys. 2010, 12, 10996–11003. [PDF]
2009
1. Gold Nanoparticles Supported on Manganese Qxides for Low Temperature CO Oxidation, L. C. Wang, Q. Liu, X. S. Huang, Y. M. Liu, Y. Cao*, K. N. Fan, Appl. Catal. B: Environ.2009, 88, 204-212. [PDF]
2. Dry Citrate-precursor Synthesized Nanocrystalline Cobalt Oxide as Highly Active Catalyst for Total Oxidation of Propane, Q. Liu, L. C. Wang, M. Chen, Y. Cao*, H. Y. He, K. N. Fan,J. Catal. 2009, 263, 104-113. [PDF]
3. Morphology Effects of Nanoscale Ceria on the Activity of Au/CeO2 Catalysts for Low-temperature CO Oxidation, X. S. Huang, H. Sun, L. C. Wang, Y. M. Liu*, K. N. Fan, Y. Cao*, Appl. Catal. B: Environ. 2009, 90, 224-232. [PDF]
4. A Green and Efficient Oxidation of Alcohols by Supported Gold Catalysts using Aqueous H2O2 under Organic Solvent-free Conditions, J. Ni, W. J. Yu, L. He, H. Sun, Y. Cao*, H. Y. He, K. N. Fan, Green Chem. 2009, 11, 756-759. [PDF][SI]
5. Effect of Pretreatment Atmosphere on CO Oxidation over α-Mn2O3 Supported Gold Catalysts, L. C. Wang, L. He, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, J. H. Zhuang*, J. Catal. 2009, 264, 145-153. [PDF]
6. Gold Supported on Hydroxyapatite as Versatile Multifunctional Catalyst for the Direct Tandem Synthesis of Imines and Oximes, H. Sun, F. Z. Su, J. Ni, Y. Cao*, H. Y. He, K. N. Fan, Angew. Chem. Int. Ed. 2009, 48, 4390-4393. [PDF] [SI]
7. Photooxygenation of Hydrocarbons over Efficient and Reusable Decatungstate Heterogenized on Hydrophobically Modified Mesoporous Silica, L. L. Ni, J. Ni, Y. Lv, P. Yang*, Y. Cao*, Chem. Commun. 2009, 2171-2173. [PDF] [SI]
8. 精細化學品綠色合成中的納米Au催化：機遇與挑戰, 何林, 倪吉, 孫浩, 曹勇, 催化學報，2009, 30, 958-964. [PDF]
9. Highly Selective Ce-Ni-O Catalysts for Efficient Low Temperature Oxidative Dehydrogenation of Propane, Y. M. Liu, L. C. Wang, M. Chen, J. Xu, Y. Cao*, H. Y. He, K. N. Fan, Catal. Lett. 2009, 130, 350-354. [PDF]
10. The Role of the Promoters in Cu Based Catalysts for Methanol Steam Reforming, G. S. Wu, D. S. Mao, G. Z. Lu, Y. Cao*, K. N. Fan, Catal. Lett. 2009, 130, 177-184. [PDF]
11. Aqueous Room Temperature Gold-catalyzed Chemoselective Transfer Hydrogenation of Aldehydes, L. He, J. Ni, L. C. Wang, F. J. Yu, Y. Cao*, H. Y. He, K. N. Fan, Chem. Eur. J.2009, 15, 11833-11836. [PDF] [SI]
12. Efficient Room Temperature Gold-catalyzed Selective Reduction of Nitro Compounds using CO and H2O as the Hydrogen Source, L. He, L. C. Wang, H. Sun, J. Ni,Y. Cao*, H. Y. He, K. N. Fan, Angew. Chem. Int. Ed. 2009, 48, 9538-9541. [PDF] [SI]
13. Mesostructured CeO2as an Effective Catalyst for Styrene Synthesis by Oxidative Dehydrogenation of Ethylbenzene, J. Xu, L. C. Wang, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Catal. Lett. 2009,133, 307-313. [PDF]
14. Vanadia Supported on H2O2 -detemplated Mesoporous SBA-15 as New Effective Catalysts for the Oxidative Dehydrogenation of Propane, J. Xu, M. Chen, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan*, Micro. Meso. Mat. 2009, 118, 354-360. [PDF]
2008
1. Ga-Al Mixed-Oxide-Supported Gold Nanoparticles with Enhanced Activity for Aerobic Alcohol Oxidation, F. Z. Su, Y. M. Liu, L. C. Wang, Y. Cao*, H. Y. He, K. N. Fan, Angew. Chem. Int. Ed. 2008, 47, 334-337. [PDF] [SI]
2. Aerobic Oxidation of Alcohols Catalyzed by Gold Nanoparticles Supported on Gallia Polymorphs, F. Z. Su, M. Chen, L. C. Wang, X. S. Huang, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Catal. Commun. 2008, 9, 1027-1032. [PDF]
3. Waste-free Soft Reactive Grinding Synthesis of High-surface-area Copper-manganese Spinel Oxide Catalysts Highly Effective for Methanol Steam Reforming, Q. Liu, L. C. Wang, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Catal. Lett. 2008, 121, 144-150. [PDF]
4. Simple Fabrication of Thermally Stable Apertured N-doped TiO2 Microtubes as a Highly Efficient Photocatalyst under Visible Light Irradiation, J. H. Xu, W. L. Dai, J. X. Li, Y. Cao, H. X. Li, H. Y. He, K. N. Fan, Catal. Commun. 2008, 9, 146-152. [PDF]
5. Simple Fabrication of Twist-like Helix N,S-codoped Titania Photocatalyst with Visible-light Response, J. H. Xu, J. X. Li, W. L. Dai, Y. Cao, H. X. Li, K. N. Fan, Appl. Catal. B: Environ. 2008, 79, 72-80. [PDF]
6. Novel Core-shell Structured Mesoporous Titania Microspheres: Preparation, Characterization and Excellent Photocatalytic Activity in Phenol Abatement, J. H. Xia, W. L. Dai, J. X. Li, Y. Cao, H. X. Li, K. N. Fan, J. Photochem. Photobiol. A, Chem. 2008, 195, 284–294 [PDF]
7. MnO2 Nanorod Supported Gold Nanoparticles with Enhanced Activity for Solvent-free Aerobic Alcohol Oxidation, L. C. Wang, Y. M. Liu, M. Chen, Y. Cao*, H. Y. He, K. N. Fan,J. Phys. Chem. C 2008, 112, 6981-6987. [PDF]
8. Solvent-free Selective Oxidation of Alcohols by Molecular Oxygen over β-MnO2 Nanorods Supported Gold Nanoparticles, L. C. Wang, L. He, Q. Liu, Y. M. Liu, M. Chen, Y. Cao*, H. Y. He, K. N. Fan, Appl. Catal. A: Gen. 2008, 344, 150-157. [PDF]
9. Dehydrogenation of Propane over Spinel-type Gallia-alumina Solid Solution Catalysts, M. Chen, F. Z. Su, J. Xu, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, J. Catal. 2008, 256, 293-300. [PDF]
10. Enhanced Activity of Spinel-type Ga2O3–Al2O3 Mixed Oxide for the Dehydrogenation of Propane in the Presence of CO2 , M. Chen, J. Xu, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan,Catal. Lett. 2008, 124, 369-375. [PDF]
11. Aluminum Containing MCF Silica as Highly Efficient Solid Acid Catalyst for Alcohol Esterification, Y. M. Liu, J. Xu, L. C. Wang, Y. Cao*, H. Y. He, K. N. Fan, Catal. Lett. 2008,125, 62-68. [PDF]
12. Efficient and Chemoselective Reduction of Carbonyl Compounds with Supported Gold Catalysts under Transfer Hydrogenation Conditions, F. Z. Su, L. He, J. Ni, Y. Cao*, H. Y. He, K. N. Fan, Chem. Commun. 2008, 3531-3533. [PDF] [SI]
13. Gold Supported on Nanocrystalline β-Ga2O3 as Versatile Bifunctional Catalyst for Facile Oxidative Transformation of Alcohols, Aldehydes and Acetals into Esters, F. Z. Su, J. Ni, H. Sun, Y. Cao*, H. Y. He, K. N. Fan, Chem. Eur. J. 2008, 14, 7131-7135. [PDF] [SI]
14. Gold Nanoparticles Deposited on Manganese (III) Oxide as Novel Efficient Catalyst for Low Temperature CO Oxidation, L. C. Wang, X. S. Huang, Q. Liu, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, J. H. Zhuang*, J. Catal. 2008, 259, 66-74. [PDF]
15. Facile Synthesis of Fe-loaded Mesoporous Silica by a Combined Detemplation-incorporation Process through Fenton’s Chemistry, Y. M. Liu, J. Xu, L. He, Y. Cao*, H. Y. He, D. Y. Zhao, J. H. Zhuang*, K. N. Fan, J. Phys. Chem. C2008, 112, 16575-16583. [PDF]
2007
1. An Integrated Low Temperature Approach to Highly Photoactive Nanocrystalline Mesostructured Titania, J. Zhu, Z. F. Bian, J. Ren, Y. Cao*, Y. M. Liu, W. L. Dai, H. Y. He, K. N. Fan, Catal. Commun. 2007, 8, 971-976. [PDF]
2. Production of Hydrogen by Steam Reforming of Methanol over Cu/ZnO Catalysts Prepared via a Practical Soft Reactive Grinding Route Based on Dry Oxalate-precursor Synthesis, L. C. Wang, Y. M. Liu, M. Chen, Y. Cao*, H. Y. He, G. S. Wu, W. L. Dai, K. N. Fan, J. Catal. 2007, 246, 193-204. [PDF]
3. 高性能納米金催化劑的研究進展, 王路存, 蘇方正, 黃新松, 曹勇, 石油化工, 2007, 9, 867-873.
4. 選擇氧化中新型Keggin結構硅鎢酸鹽催化劑的研究進展, 李靜霞, 戴維林, 曹勇, 范康年, 石油化工, 2007, 4, 412-417.
5. Microwave Accelerated Solvent-free Aerobic Oxidation of Benzyl Alcohol over Efficient and Reusable Manganese Oxides, Y. Su, L. C. Wang, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan,Catal. Commun. 2007, 8, 2181-2185. [PDF]
6. Nanocrystalline Anatase TiO2 Photocatalysts Prepared via a Facile Low Temperature Nonhydrolytic Sol-gel Reaction of TiCl4 and Benzyl Alcohol, J. Zhu, J. Yang, Z. F. Bian, J. Ren, Y. M. Liu, Y. Cao*, H. X. Li, H. Y. He, K. N. Fan*, Appl. Catal. B: Environ. 2007, 76, 82-91. [PDF]
7. New Green Catalytic Manufacture of Glutaric Acid from the Oxidation of Cyclopentane-1,2-diol with Aqueous Hydrogen Peroxide, H. Chen, W. L. Dai, R. H. Gao, Y. Cao*, H. X. Li, K. N. Fan, Appl. Catal. A: Gen. 2007,328, 226-236. [PDF]
8. A Green Pocess For O-heterocyclization of Cycloocta-1,5-diene by Peroxotungstic Species with Aqueous H2O2, R. H. Gao, W. L. Dai, Y. Y. Le, X. L. Yang, Y. Cao, H. X. Li, K. N. Fan, Green Chem. 2007, 9, 878-881. [PDF]
9. Structural Evolution and Catalytic Properties of Nanostructured Cu/ZrO2 Catalysts Prepared by Oxalate Gel-coprecipitation Technique, L. C. Wang, Q. Liu, M. Chen, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, J. Phys. Chem. C2007, 111, 16549-16557. [PDF]
10. Production of hydrogen by steam reforming of methanol over Cu/ZnO catalysts prepared via a practical soft reactive grinding route based on dry oxalate-precursor synthesis, L. C. Wang, Y. M. Liu, Y. Cao*, G. S. Wu, C. Z. Yao, W. L. Dai, H. Y. He, K. N. Fan,J. Catal.2007, 246, 193-204. [PDF]
2006
1. Chromium Supported on Mesocellular Silica Foam (MCF) for Oxidative Dehydrogenation of Propane, Y. M. Liu, W. L. Feng, L. C. Wang, Y. Cao, W. L. Dai, H. Y. He, K. N. Fan,Catal. Lett. 2006, 106, 145-152. [PDF]
2. Highly Effective Hydrogen Production from Steam Reforming of Methanol over SBA-15-Promoted Cu/ZnO/Al2O3 Catalysts, C. Z. Yao, X. R. Zhang, L. C. Wang, Y. Cao, W. L. Dai, K. N. Fan, D. Wu, Y. H. Sun, Acta Chimica Sinica2006, 64, 269-272. [PDF]
3. Structure and Catalytic Properties of Vanadium Oxide Supported on Mesocellulous Silica Foams (MCF) for the Oxidative Dehydrogenation of Propane to Propylene, Y. M. Liu, W. L. Feng, T. C. Li, H. Y. He, W. L. Dai, Y. Cao*, K. N. Fan, J. Catal. 2006, 239, 125-136. [PDF]
4. A Low Temperature Benzyl Alcohol Alcoholysis Approach to Highly Photoactive Nanocrystalline Anatase TiO2, J. Zhu, J. Yang, L. Chen, Y. Cao, W. L. Dai, K. N. Fan, Chinese J. Catal. 2006, 27, 171-177.
5. Transformation of Various Oxygen Species on the Surface of Electrolytic Silver Characterized by in Situ Raman Spectroscopy, L. P. Ren, W. L. Dai, X. L. Yang, Y. Cao, Z. K. Xie, K. N. Fan, Chinese J. Catal. 2006, 27, 115-118. [PDF]
6. Highly Photoactive Nanocrystalline TiO2 Aerogel Synthesized by a Facile Epoxide-mediated Non-alkoxide Sol-gel Method, L. Chen, J. Zhu, J. Yang, Y. M. Liu, Y. Cao, Y. M. Liu, H. Y. He, W. L. Dai, K. N. Fan, Chinese J. Catal. 2006, 27, 291-293.
7. On the Role of Reverse Hydrogen and Water Spillover for Methanol Decomposition over Cu/ZrO2 Catalyst, G. S. Wu, L. C. Wang, Y. M. Liu, Y. Cao, W. L. Dai, H. Y. He, K. N. Fan,Acta Chimica Sinica2006, 64, 1017-1021.
8. Implication of the Role of Oxygen Anions and Oxygen Vacancies for Methanol Decomposition over Zirconia Supported Copper Catalysts, G. S. Wu, L. C. Wang, Y. M. Liu, Y. Cao*, W. L. Dai, H. Y. He, K. N. Fan*, Appl. Surf. Sci. 2006, 253, 974-982. [PDF]
9. Photocatalytic Activity of Epoxide Sol-gel Derived Titania Transformed into Nanocrystalline Aerogel Materials by Supercritical Drying, L. Chen, J. Zhu, Y. M. Liu,Y. Cao*, H. X. Li, W. L. Dai, H. Y. He, K. N. Fan, J. Mol. Catal. A, Chem. 2006, 255, 260-268. [PDF]
10. Studies on the Structural Change of a Reaction-controlled Phase-transfer [p-C5H5NC16H33]3 {PO4[WO3]4} Catalyst during the Selective Oxidation of Cyclopentene to Glutaric Acid with Aqueous H2O2, H. Chen, W. L. Dai, X. L. Yang, R. H. Gao, Y. Cao, H. X. Li, K. N. Fan, Appl. Catal. A: Gen. 2006, 309, 62-69. [PDF]
11. Tungsten Containing MCF Silica as Active and Recyclable Catalysts for Liquid-phase Oxidation of 1,3-butanediol to 4-hydroxy-2-butanone, Y. Su, Y. M. Liu, L. C. Wang, M. Chen, Y. Cao*, W. L. Dai, H. Y. He, K. N. Fan*, Appl. Catal. A: Gen. 2006, 315, 91-100. [PDF]
12. Effect of Preparation Method on the Hydrogen Production from Methanol Steam Reforming over Binary Cu/ZrO2 Catalysts, C. Z. Yao, L. C. Wang, Y. M. Liu, G. S. Wu, Y. Cao*, W. L. Dai, H. Y. He, K. N. Fan*, Appl. Catal. A: Gen. 2006, 297, 151-158. [PDF]
13. 環戊烯選擇氧化合成戊二酸綠色催化過程, 陳慧, 戴維林, 高瑞華, 楊新麗, 曹勇, 范康年, 石油化工, 2006, 35, 118-121.
2005
1. Synthesis, Characterization and Catalytic Application of Mesoporous W-MCM-48 for the Selective Oxidation of Cyclopentene to Glutaraldehyde, X. L. Yang , W. L. Dai, R. H. Gao, H. Chen, H. X. Li, Y. Cao, K. N. Fan, J. Mol. Catal. A-Chem. 2005, 241, 205-214. [PDF]
2. Novel Tungsten-containing Mesoporous HMS Material: Its Synthesis, Characterization and Catalytic Application in the Selective Oxidation of Cyclopentene to Glutaraldehyde by Aqueous H2O2, X. L. Yang, W. L. Dai, J. H. Xu, Y. Cao, H. X. Li, K. N. Fan, Appl. Catal. A: Gen. 2005, 283, 1-8. [PDF]
3. Highly Efficient Ni-Ce-O Mixed Oxide Catalysts via Gel-coprecipitation of Oxalate Precursors for Catalytic Combustion of Methane, N. Yi, Y. Cao, Y. M. Liu, W. L. Dai, H. Y. He, K. N. Fan, Chem. Lett. 2005, 34, 108-109.
4. Microwave-irradiation Promoted Cu/ZnO/Al2O3 Catalyst for Hydrogen Production from Steam Reforming of Methanol, X. R. Zhang, C. Z. Yao, L. C. Wang, Y. Cao, D. Wu, Y. H. Sun, W. L. Dai, K. N. Fan, Chem. J. Chin. Univ.-Chin. 2005, 26, 1137-1139.
5. Gas-phase Photo-oxidations of Organic Compounds over Different forms of Zirconia, C. Y. Wu, X. P. Zhao, Y. J. Ren, Y. H. Yue, W. M. Hua, Y. Cao, Y. Tang, Z. Gao, J. Mol. Catal. A, Chem. 2005, 229, 233–239. [PDF]
6. Carbon Exchange between Methane and Carbon Dioxide over Rh/H-BEA, L. P. Qian, Y. Cao, B. Yue, Yu Ren, B. L. Chen, H. Y. He, Chinese J. Catal. 2005, 26, 455-457. [PDF]
7. A Highly Efficient Cu/ZnO/Al2O3 Catalyst via Gel-coprecipitation of Oxalate Precursors for Low-temperature Steam Reforming of Methanol, X. R. Zhang, L. C. Wang, C. Z. Yao, Y. Cao*, W. L. Dai, H. Y. He, K. N. Fan, Catal. Lett. 2005, 102, 183-190. [PDF]
8. Synthesis of Novel Core-shell Structured WO3/TiO2 Spheroids and Its Application in the Catalytic Oxidation of Cyclopentene to Glutaraldehyde by Aqueous H2O2, X. L. Yang, W. L. Dai, C. W. Guo, Chen H, Y. Cao, H. X. Li, H. Y. He, K. N. Fan, J. Catal. 2005, 234, 438-450. [PDF]
9. Nanocrystalline LaCoO3 Perovskites Confined in SBA-15 Silica as New Efficient Catalysts for Hydrocarbon Oxidation, N. Yi, Y. Cao*, Y. Su, W. L. Dai, H. Y. He, K. N. Fan*, J. Catal.2005, 230, 249-253. [PDF]
10. A Unique Microwave Effect on the Microstructural Modification of Cu/ZnO/Al2O3Catalysts for Steam Reforming of Methanol, X. R. Zhang, L. C. Wang, Y. Cao*, W. L. Dai, H. Y. He, K. N. Fan*, Chem. Commun. 2005, 32, 4104-4106. [PDF] [SI]
11. Direct Dehydrogenation of Methanol to Formaldehyde over Pre-treated Polycrystalline Silver Catalyst, L. P. Ren, W. L. Dai, X. L. Yang, J. H. Xu, Y. Cao, H. X. Li, K. N. Fan,Catal. Lett. 2005, 99, 83-87. [PDF]
12. 新型鈾基催化劑的研究進展, 高瑞華, 戴維林, 楊新麗, 曹勇, 范康年, 石油化工, 2005, 34, 791-796.
13. 新型WO3/HMS催化劑的合成及其在環戊烯選擇氧化反應中的性能研究, 楊新麗, 戴維林, 徐建華, 陳浩, 曹勇, 范康年, 催化學報, 2005, 26, 311-316.
2004
1. A Density Functional Theory Study on the Adsorption of Chlorobenzene on the Si(111)-7 × 7 Surface, Z. H. Li, Y. C. Li, W. N. Wang, Y. Cao, K. N. Fan, J. Phys. Chem. B 2004, 108, 14049-14055. [PDF]
2. Novel Highly Active Ag-SiO2-Al2O3-ZnO Catalyst for the Production of Anhydrous HCHO from Direct Dehydrogenation of CH3OH, L. P. Ren, W. L. Dai, X. L. Yang, Y. Cao, K. N. Fan, Appl. Catal. A: Gen. 2004, 273, 83-88. [PDF]
3. Novel Efficient and Green Approach to the Synthesis of Glutaraldehyde over Highly Active W-doped SBA-15 Catalyst, X. L. Yang, W. L. Dai, H. Chen, Y. Cao, H. X. Li, H. Y. He, K. N. Fan, J. Catal. 2004, 229, 259-263.[PDF]
4. Synthesis and Characterization of Thermally Stable Mesostructured Sulfated Zirconia by a Novel Sulfate-assisted Alcohothermal Route, N. Yi, Y. Cao*, W. L. Feng, W. L. Dai, K. N. Fan, Catal. Lett. 2004, 99, 73-78. [PDF]
5. Catalytic Oxidation of Methane over Novel Ce-Ni-O Mixed Oxide Catalysts Prepared by Oxalate Gel-coprecipitation, N. Yi, Y. Cao*, W. L. Feng, W. L. Dai, K. N. Fan, Catal. Lett.2004, 99, 207-213. [PDF]
6. Highly Effective Hydrogen Production from Steam Reforming of Methanol over Cu/ZnO/Al2O3 Catalysts Promoted by Nanostructured Carbon Materials, X. R. Zhang, L. C. Wang, C. Z. Yao, Y. Cao, W. L. Dai, K. N. Fan, Chem. J. Chin. Univ.-Chin. 2004, 25, 2125-2127.
7. Effect of Promoter on the Structure and Performance of Activated Carbon-supported Wacker-type Catalyst for DMC Synthesis, P. Yang, Y. Cao, X. H. Bao, W. L. Dai, K. N. Fan, Chinese J. Catal. 2004, 25, 995-999.
8. A Remarkable Effect of Alkali Addition in the Oxidative Carbonylation of Methanol to Dimethyl Carbonate Catalyzed by a Polymer-complexed Cu(II) Catalyst System, W. L. Feng, Y. Cao*, N. Yi, W. L. Dai, K. N. Fan*, Chem. Lett. 2004, 33, 958-959. [PDF]
9. Direct Production of Hydrogen Peroxide from CO, O2, and H2O Over a Novel Alumina Supported Cu Catalyst, W. L. Feng, Y. Cao*, N. Yi, W. L. Dai, K. N. Fan*, New J. Chem.2004, 28, 14311-14333. [PDF]
10. Ni-Ce-O Mixed Oxide via Gel-coprecipitation of Oxalate Precursors for Catalytic Combustion of Methane, N. Yi, Y. Cao, W. L. Dai, H. Y. He, K. N. Fan, Chinese J. Catal.2004, 26 (1), 7-9.
11. Ag-SiO2-Al2O3 Composite as Highly Active Catalyst for the Formation of Formaldehyde from Partial Oxidation of Methanol, W. L. Dai, Y. Cao, L. L. Ren, X. L. Yang, J. H. Xu, H. Y. He, K. N. Fan, J. Catal. 2004, 228, 80-91. [PDF]
12. Vanadium Oxide Supported on Mesoporous SBA-15 as Highly Selective Catalysts in the Oxidative Dehydrogenation of Propane, Y. M. Liu, Y. Cao*, N. Yi, W. L. Feng, W. L. Dai, S. R. Yan, H. Y. He, K. N. Fan*, J. Catal. 2004, 224, 417-428. [PDF]
13. Impact of Preparation Strategy on the Properties of Carbon-supported Wacker-type Catalysts in Vapor-phase Dimethyl Carbonate Synthesis, Y. Cao*, P. Yang, C. Z. Yao, N. Yi, W. L. Feng, W. L. Dai, K. N. Fan*, Appl. Catal. A: Gen. 2004, 272, 15-22. [PDF]
14. A Novel Non-phosgene Process for the Synthesis of Methyl N-phenyl Carbamate from Methanol and Phenylurea, Effect of Solvent and Catalyst, X. K. Wang, S. R. Yan, Y. Cao, K. N. Fan, H. Y. He, M. Q. Kang, S. Y. Peng, Chinese J. Chem. 2004, 22, 782-786.
15. 納米氧化鈰催化苯甲酸甲酯催化氫化合成苯乙酮, 王少成, 陳庚, 曹勇, 沈偉, 胡建國,徐華龍, 復旦學報, 2004, 43, 615-620. [PDF]
16. 新型介孔釩氧化物催化劑上丙烷高選擇性氧化脫氫制丙烯研究, 伊楠, 劉永梅, 馮偉樑,曹勇, 戴維林, 范康年, 吳東, 孫予罕, 復旦學報, 2004, 43, 597-602. [PDF]
17. 新型MCM-41固載化鈮酸催化氧化環戊烯制備戊二醛, 徐建華, 戴維林, 楊新麗, 曹勇,范康年, 化學學報, 2004, 62, 1467-1471. [PDF]
2003
1. Multiple Configurations of N-methylpyrrole Binding on Si(111)-7×7, F. Tao, Z. L. Yuan, X. F. Chen, M. H. Qiao, Z. H. Wang, Y. J. Dai, H. G. Huang, Y. Cao, G. Q. Xu, Phys. Rev. B2003, 67, 245406. [PDF]
2. Novel Highly Active Ag-SiO2-MgO Catalysts used for Direct Dehydrogenation of Methanol to Anhydrous Formaldehyde, L. P. Ren, W. L. Dai, Y. Cao, K. N. Fan, Catal. Lett. 2003,85, 81-85.
3. Dissociative Adsorption of Pyrrole on Si(111)-(7×7), Z. L. Yuan, X. F. Chen, Z. H. Wang, Y. Cao, K. S. Yong, Q. P. Liu, G. Q. Xu, J. Chem. Phys. 2003, 119, 10389-10395.
4. Preparation of High Performance Cu/ZnO/Al2O3 Catalyst for Methanol Synthesis from CO2Hydrogenation by Coprecipitation-reduction, Y. Cao, L. F. Chen，W. L. Dai, K. N. Fan, D. Wu，Y. H. Sun, Chem. J. Chin. Univ.-Chin. 2003, 24, 1296-1298.
5. Novel Economic and Green Approach to the Synthesis of Highly Active W-MCM41 in Oxidative Cleavage of CPE, W. L. Dai, H. Chen, H. X. Li, Y. Cao, K. N. Fan, Chem. Commun. 2003, 892-893. [PDF]
6. Amperometric Biosensor Based on a Nanoporous ZrO2 Matrix, B. H. Liu, Y. Cao, Ddadan Chen, J. L. Kong, J. Q. Deng, Anal. Chim. Acta. 2003, 478, 59-66. [PDF]
7. First Observation of Highly Efficient Dehydrogenation of Methanol to Anhydrous Formaldehyde over Novel Ag-SiO2-MgO-Al2O3 Catalyst, L. P. Ren, W. L. Dai, Y. Cao, H. X. Li, K. N. Fan, Chem. Commun. 2003, 3030-3031. [PDF]
8. Fabrication of Mesoporous Core-shell Structured Titania Microspheres with Hollow Interiors, C. W. Guo, Y. Cao*, S. H. Xie, W. L. Dai, K. N. Fan, Chem. Commun. 2003,700-701. [PDF]
9. Adsorption and Thermal Dissociation of Pyrrole on Si(100)-2×1, M. H. Qiao, F. Tao,Y. Cao, G. Q. Xu, Surf. Sci. 2003, 544, 285-294. [PDF]
10. 45. Mesoporous Bimetallic PdCl2-CuCl2 Catalysts for Dimethyl Carbonate Synthesis by Vapor Phase Oxidative Carbonylation of Methanol, P. Yang, Y. Cao, J. C. Hu, W. L. Dai, K. N. Fan, Appl. Catal. A: Gen. 2003, 241, 363-373. [PDF]
11. Effect of Chemical Treatment of Activated Carbon as a Support for Promoted Dimethyl Carbonate Synthesis by Vapor Phase Oxidative Carbonylation of Methanol over Wacker-type Catalysts, P. Yang, Y. Cao, W. L. Dai, J. F. Deng, K. N. Fan, Appl. Catal. A: Gen.2003, 243, 323-331. [PDF]
12. Highly Effective Oxidative Dehydrogenation of Propane over Vanadia Supported on Mesoporous SBA-15 Silica, Y. M. Liu, Y. Cao, W. L. Dai, K. N. Fan, Catal. Lett. 2003, 88, 61-67. [PDF]
13. CuCl Catalyst Heterogenized on Diamide Immobilized SBA-15 for Efficient Oxidative Carbonylation of Methanol to Dimethylcarbonate, Y. Cao*, J. C. Hu, P. Yang, W. L. Dai, K. N. Fan*, Chem. Commun. 2003, 908-909. [PDF] [SI]
14. The Non-isothermal Decomposition Kinetics of Copper(II) Complexes with Phthalanilic Acids and Amino Acids, L. P. Ren, W. L. Dai, H. X. Li, Y. Cao, X. H. Zhang, K. N. Fan, Int. J. Chem. Kinet. 2003, 35, 623-628.
15. 表征固體超強酸性的新方法——正丁烷異構化反應的原位13C MAS NMR譜, 馬卓娜, 胡軍成, 范康年, 曹勇, 賀鶴勇, 高滋, 化學學報, 2003, 61, 1352-1356. [PDF]
16. 納米Ni-Co-B非晶態合金抗氧化行為的原位XPS研究, 戴維林, 曹勇, 范康年, 鄧景發, 高等學校化學學報, 2003, 3, 473-476. [PDF]
17. 規則中孔TiO2微球的均相沉淀合成及其在環戊烯氧化反應中的應用, 郭昌文, 戴維林,曹勇, 范康年, 高等學校化學學報, 2003, 24, 1097-1099. [PDF]
18. 氧在銀/二氧化硅催化劑上的超高真空程序升溫脫附研究, 任麗萍, 戴維林, 董義, 喬明華, 曹勇, 范康年, 李和興, 催化學報, 2003, 24, 669-673. [PDF]
19. W-SBA-15的原位合成及其在環戊烯氧化反應中的催化性能研究, 郭昌文, 戴維林, 曹勇,范康年, 化學學報, 2003, 61, 1496-1499. [PDF]
20. 甲醇脫氫制無水甲醛的高活性Ag-SiO2-Al2O3催化劑, 任麗萍, 戴維林, 曹勇, 李和興, 章文華, 范康年, 化學學報, 2003, 61, 937-940. [PDF]
2002
1. Highly Efficient VOx/SBA-15 Mesoporous Catalysts for Oxidative Dehydrogenation of Propane, Y. M. Liu, Y. Cao*, K. K. Zhu, S. R. Yan, W. L. Dai, H. Y. He, K. N. Fan*, Chem. Commun. 2002, 2832-2833. [PDF]
2. A Novel Homogeneous Catalyst Made of Poly(N-vinyl-2-pyrrolidone)-CuCl2Complex for the Oxidative Carbonylation, J. C. Hu, Y. Cao, P. Yang, J. F. Deng, K. N. Fan, J. Mol. Catal. Chem. A 2002, 185, 1-9. [PDF]
3. Evidence for the Anti-oxidation Effect of Boron on the Ultra-fine Ni-B Amorphous Alloy Catalyst, W. L. Dai, H. X. Li, Y. Cao, M. H. Qiao, K. N. Fan, J. F. Deng, Langmuir 2002,18, 9605-9608. [PDF]
4. In Situ Raman Studies on the Interaction of Oxygen and Methanol with Iodine-modified Electrolytic Silver Catalyst, W. L. Dai, Y. Dong, Y. Cao, K. N. Fan, J. F. Deng, Y. Y. Liao, B. F. Hong, J. Raman Spectr. 2002, 33, 318-324. [PDF]
5. TBAB-modified Heterogeneous Wacker-type Catalysts for Highly Selective Oxidative Carbonylation of Methanol to Dimethyl Carbonate, S. C. Wang, Y. Cao, P. Yang, J. G. Hu, D. Wu, Y. H. Sun, J. F. Deng, Chem. J. Chin. Univ.-Chin. 2002, 12, 2363-2365.
6. A Novel Method to Prepare Cu/ZnO/Al2O3 Methanol Synthesis Catalyst, Z. S. Hong, Y. Cao, J. F. Deng, K. N. Fan, Chem. J. Chin. Univ.-Chin. 2002, 23, 706-708.
7. 苯在Si(111)-7×7表面化學吸附的理論研究, 李燕茶, 王文寧, 曹勇,范康年, 化學學報, 2002,60, 653-659. [PDF]
8. A Convenient Alcohothermal Approach for Low Temperature Synthesis of CuO Nanoparticles, Z. S. Hong, Y. Cao, J. F. Deng, Mater. Lett. 2002, 52, 34-38. [PDF]
9. CO2 Hydrogenation to Methanol over Cu/ZnO/Al2O3 Catalysts Prepared by a Novel Gel-network-coprecipitation, Z. S. Hong, Y. Cao, J. F. Deng, K. N. Fan, Catal. Lett. 2002, 82, 37-44. [PDF]
10. Rare Earth (Y, La, Ce)-promoted V-HMS Mesoporous Catalysts for Oxidative Dehydrogenation of Propane, R. Zhou, Y. Cao, S. R. Yan, K. N. Fan, Appl. Catal. A: Gen.2002, 236, 103-111. [PDF]
11. 酰胺基改性的介孔MCM-41錨定Cu(II)雜化材料的合成和表征, 胡軍成, 曹勇, 楊平, 鄧景發, 范康年, 復旦學報, 2002, 41, 320-324.
12. 焙燒條件對Cu/ZnO/Al2O3甲醇催化劑的影響, 洪中山, 曹勇, 孫崎, 鄧景發, 范康年, 復旦學報,2002, 41, 330-334.
13. 負載型Ni-B非晶態合金的制備及其催化加氫活性研究, 劉波, 陳雪瑩, 莊繼華, 喬明華,曹勇, 朱源龍, 賀鶴勇, 范康年, 復旦學報, 2002, 41, 424-428.
曹勇，教授，博士生導師，男，1973年出生。1995年畢業于復旦大學化學系物理化學專業，獲理學學士學位。1998至2000年間于新加坡國立大學化學系攻讀聯合培養博士學位，2000年7月畢業于復旦大學化學系物理化學專業獲理學博士學位并留校任教至今。2001年11月破格晉升為復旦大學副教授，同年起升任碩士生導師。2005年1月破格晉升為復旦大學副教授博士生導師，同年5月升任復旦大學教授。曾主講《現代化學專題－表面化學》、《物理化學》和《催化反應機理》等課程。指導研究生多名，其中3名已獲碩士學位。
科研上主要從事表面化學和多相催化研究，涉及高性能新結構納米介孔催化材料的創制與綠色催化應用、低碳烷烴選擇氧化制烯烴、1,3-丙二醇等聚酯原料關鍵單體的催化加氫合成、金屬/半導體光催化、催化過程的原位動態譜學表征及C1資源的綜合利用等。最近主持的項目有國家自然科學基金（2項）、上海市科委納米科技專項、上海市科委科技啟明星計劃等，并參與了973項目等多項國家級和省部級重大課題研究。2004年，作為研究骨干之一，獲國家基金委優秀創新群體基金資助。在新型納米催化材料的研制及應用、催化原位譜學表征和催化理論的研究方面取得了一定的成果，累計發表論文100余篇，其中在J. Am. Chem. Soc., Angew. Chem., J. Phys. Chem. B., Langmuir, J. Chem. Phys., J. Catal., Chem. Commun., Appl. Catal., Catal. Lett., Catal. Today, Chem. Phys. Lett., New J. Chem.等SCI源刊物上發表論文180余篇；論文被國內外引用3000余次；申請中國發明專利20件（授權專利8件）；參與J. Am. Chem. Soc.、J. Catal.和《高等學校化學學報》、《化學學報》、《物理化學學報》、《石油化工》等刊物的審稿。
榮譽獎勵：
1.2014年獲得 中國催化青年獎（National Catalysis Prize for Young Scientists）
2.2009年度國家級教學成果二等獎（《微觀原理引導的大物理化學課程建設》，范康年，陸靖，唐頤，曹勇，周鳴飛，成果序號：931012）
發展多相催化新技術 創建綠色反應新體系——復旦大學曹勇教授
曹勇教授長期從事多相催化研究，在面向綠色與可持續催化應用的固體催化材料的設計、合成及表征等方面取得了一定的成績。發展了系列具有“金屬”及“表面酸／堿”等多活性位協同集成結構特征的新結構高性能催化材料設計與合成方法，實現了高分散多相金屬催化材料微結構及表面特性的精細調控。2001 年至今發表 SCI 論文 160 余篇，其中影響因子大于 3.0 論文 50 余篇，SCI他引3000 余次，10篇論文被他引40次以上，其中單篇最高他引過百次，獲得授權中國發明專利20余件。
1．基于小分子協同活化的納米金催化綠色反應新體系探索
發現并揭示了小尺寸納米 Au 對于液體甲酸低溫催化選擇分解的獨特催化性能。利用反應耦合與氫轉移策略，實現了溫和條件下納米金催化 CO/H2O 選擇還原極性不飽和鍵。揭示并闡明了反應底物與 H2O 及H2等小分子間的協同活化對于溫和條件下納米金催化腈水合以及喹啉高選擇性催化加氫制四氫喹啉等反應的重要性。以 O2及 H2O2為清潔氧源，研制出用于醇液相選擇氧化的高性能納米金催化新體系。
（1）以液體甲酸（HCOOH）為可再生能源載體的制氫／儲氫研究是當前國際上能源催化領域十分重要的課題。針對傳統 Pt 族多相貴金屬催化低溫液相甲酸分解體系存在的反應效率和選擇性偏低及穩定性不足等問題，通過對 Au 納米顆粒尺寸、催化載體及反應介質等關鍵參數的系統探究，發現并確立了一類基于“甲酸-三乙胺”為反應介質的可在環境溫度下實現甲酸高效選擇分解制氫的新型亞納米 Au/ZrO2催化體系，為認識并理解 Au 對甲酸這一在催化化學研究中最具代表性的“探針分子”的吸附及活化行為提供了新的實踐與理論依據。
（2）針對現有金催化還原存在的突出問題，先后采用以異丙醇、甲酸鹽等含氫化合物為氫源以及通過與水汽變換（CO + H2O = H2 + CO2）反應進行耦合的氫轉移（CTH）策略，成功實現了溫和條件下納米金對硝基、羰基及炔基等系列不飽和官能團的選擇可控催化還原。其中以 CO/H2O 為氫源成功實現在室溫常壓下硝基化合物金催化選擇還原的工作被遴選為熱點論文（Hot Paper）在Angew. Chem. Int. Ed. 上被予以著重介紹。
（3）在對 Au 催化 CO/H2O 還原硝基的還原機制研究中發現，H2O 解離是反應的速控步驟。受此啟發，進而發現負載納米Au 催化界面處共吸附的腈基團（CN）可顯著活化H2O 分子，使得 Au/TiO2可在80 ℃溫和條件下高效催化多類有機腈選擇水解至相應的酰胺化合物。該發現被列選為ChemSusChem刊物當期封面論文。據此進一步探索研究了 H2與喹啉在納米 Au 上的“協同活化”行為。H2/D2交換等系列研究表明，含有堿性基團的喹啉在溫和條件下可顯著促進納米 Au 對H2的催化活化。由此成功實現了利用TiO2負載Au 催化喹啉選擇加氫高選擇性高收率制取藥物合成中極為重要的四氫喹啉化合物。與同等條件下Pd、Pt 等傳統貴金屬表現截然不同的是，在該反應中Au 不但未表現出因反應底物強吸附導致的中毒失活現象，反而表現出獨特的“底物自促進效應”。
（4）在對以 O2為氧源的醇液相選擇氧化研究中，從載體設計與優化入手，以具獨特脫氫特性的Ga-Al 復合氧化物為載體獲得了高活性的Au/Ga3Al3O9催化劑。與此同時，針對“非活潑”脂肪醇的選擇氧化，嘗試將H2O2引入納米金催化醇氧化反應中，發現H2O2-Au/TiO2對于脂肪醇選擇氧化特別有效，為納米金在環境友好選擇氧化中的應用開拓了新方向。相關系列論文自 2008 年以來已獲包括Chem. Rev.、Chem. Soc. Rev.、Angew. Chem.、J. Am. Chem. Soc.等在內的一流期刊 150 余次引用與評述。
2．涉及多活性位協同集成的多相催化級聯反應體系的構建
揭示并闡明了多活性位協同集成及級聯反應策略用于調控反應通道及實現高選擇性綠色合成的重要性，發展出從醇、硝基化合物等簡單原料出發“一步”清潔合成酯、亞胺、仲胺、喹啉及偶氮化合物等精細復雜分子的幾類高性能納米 Au 及Ir基催化反應新體系；以氧化鋯為載體制備了同時對甲酸分解制氫與生物基乙酰丙酸的選擇還原制γ-戊內酯以及甘油氫解制正丙醇具高活性的新型納米Au/ZrO2與Ir/ZrO2系列催化劑，在探索將固體催化材料用于生物質原料高值利用方面取得了進展。
（1）盡可能減少復雜精細有機分子合成所需的反應步驟是現代合成化學所面臨的重要挑戰之一。以“多活性位協同集成”概念為指導可望研制出用于綠色級聯合成的高效“多功能”固體催化劑。設計了一類兼具“選擇氧化”及“催化縮合”雙功能特性的Au/-Ga2O3催化體系，成功實現了醇、醛等化合物溫和條件下“一步”法直接選擇氧化制取在香料工業中極為重要的芳酯類化合物。基于類似思路，利用兼具酸堿及氧化等“多功能”特性的磷灰石載 Au 催化體系成功實現了亞胺、肟及具生理活性的α-氨基亞磷酸酯類化合物等重要精細中間體的高效、清潔、簡約合成，為“多活性位協同集成”策略在藥物中間體等復雜精細有機分子綠色合成領域中的應用提供了新范例。
（2）基于有關氧化物載Au催化體系兼具良好“醇脫氫活化”及“轉移加氫”性能的發現，在TiO2負載的小尺寸納米Au（～2 nm）催化劑上實現了計量胺／醇經“脫氫–縮合–加氫”等多級連續步驟的“一步式借氫偶聯”高選擇性合成仲胺類化合物的反應。最近還進一步實現了以醇為烷基化試劑的納米Au催化廉價硝基化合物一步N-烷基化高選擇性合成仲胺及叔胺等高級胺的反應。采用類似策略，在對以Au為主的催化活性金屬的篩選中，發現TiO2負載的亞納米Ir可直接催化硝基與乙醇等低碳醇高收率直接合成喹啉化合物。在上述發現基礎上，最近通過對載體表面酸、堿及Au加氫活性位濃度的精細調控與優化，進一步實現了對芳硝基選擇加氫過程反應通道的調控，并實現了以防硝基為原料對液晶、染料及藥物合成中重要的偶氮類化合物的直接加氫合成。
“多活性協同位集成”用于高性能固體催化劑設計研究思路對于面向可持續綠色合成的催化體系的創制及發展節能降耗的過程強化技術具重要意義，此方向系列論文已獲包括Chem. Rev.和Natutre Chemistry等在內的一流期刊80余次引用與評述。
（3）為應對日益嚴峻的能源與資源危機，世界各國近年來高度重視可再生的纖維素等生物質資源的開發利用。在發展“不用 H2”的生物質精煉催化新體系研究方面，以 ZrO2負載亞納米 Au 為催化劑實現了以甲酸為價廉替代氫源選擇還原乙酰丙酸制-戊內酯這一重要的可再生高值化學品，解決了長期以來加氫脫氧等關鍵過程所面臨的依賴化石源 H2等問題；在實用可行的生物質精煉催化新體系的創設方面，進一步發展了Cu/ZrO2催化甲酸選擇氫解甘油等過程的非貴金屬催化體系；在面向可再生大宗化學品合成的非石油基催化路線的設計與構建方面，提出并發展了一條經由正丙醇關鍵中間體的甘油“選擇氫解–脫水”生物質制丙烯增產新技術。
來源：科學成果管理與研究 2015年第8期
中國科技創新人物云平臺暨“互聯網+”科技創新人物開放共享平臺（簡稱：中國科技創新人物云平臺）免責聲明：
1、中國科技創新人物云平臺是：“互聯網+科技創新人物”的大型云平臺，平臺主要發揮互聯網在生產要素配置中的優化和集成作用，將互聯網與科技創新人物的創新成果深度融合于經濟社會各領域之中，提升實體經濟的創新力和生產力，形成更廣泛的以互聯網為基礎設施和實現工具的經濟發展新形態，實現融合創新，為大眾創業，萬眾創新提供智力支持，為產業智能化提供支撐，加快形成經濟發展新動能，促進國民經濟提質增效升級。
2、中國科技創新人物云平臺暨“互聯網+”科技創新人物開放共享平臺內容來源于互聯網，信息都是采用計算機手段與相關數據庫信息自動匹配提取數據生成，并不意味著贊同其觀點或證實其內容的真實性，如果發現信息存在錯誤或者偏差，歡迎隨時與我們聯系，以便進行更新完善。
3、如果您認為本詞條還有待完善，請編輯詞條。
4、如果發現中國科技創新人物云平臺提供的內容有誤或轉載稿涉及版權等問題，請及時向本站反饋，網站編輯部郵箱：kjcxac@126.com。
5、中國科技創新人物云平臺建設中盡最大努力保證數據的真實可靠，但由于一些信息難于確認不可避免產生錯誤。因此，平臺信息僅供參考，對于使用平臺信息而引起的任何爭議，平臺概不承擔任何責任。
點擊圖片查看原圖
